Thus, the reduction of Fe 3+ to Fe 2+ greatly limits the treatment performance of the Fenton reaction for pollutants degradation. As a result, Fe 3+ is massively accumulated from the oxidation of Fe 2+ in the Fenton reaction system since Fe 2+ regeneration from Fe 3+ is very slow ( Qiang et al., 2003). Besides, most of the Fenton reagents are added at once while over-dosage of either H 2O 2 or iron ions would lead to side reactions ( Eq. The increased salt content probably makes this wastewater unacceptable for natural environments or poses significant pressure on the subsequent reverse osmosis unit ( Wang et al., 2014 Fang et al., 2018). In addition, the employment of iron salt inevitably increases water salinity ( Li et al., 2013). In addition, massive alkaline reagents were also consumed for the subsequent neutralization of the treated solution. However, working in such acidic pH requires the addition of a large amount of acid. The addition of concentrated acid reagent is indispensable to adjust the solution pH to ∼3.0, that is the optimum condition for the Fenton reaction. However, the Fenton process has some drawbacks, which greatly hamper its industrial application ( Babuponnusami and Muthukumar, 2014 Gao et al., 2020). 2), maintaining the continuous Fenton reaction ( Babuponnusami and Muthukumar, 2014 Bello et al., 2019). The second stage is characterized by a slow reaction between Fe 3+ and H 2O 2 for the regeneration of Fe 2+ ( Eq. 1), most of the pollutant degradation is achieved in this stage. OH from the homogeneous reaction between Fe 2+ and H 2O 2 ( Eq.The first stage is characterized by the rapid formation of The Fenton reaction mainly proceeds via two steps ( Neyens and Baeyens, 2003 Moreira et al., 2017 Gao et al., 2020). Among various AOPs, the conventional Fenton reaction process has been most widely applied for the treatment of wastewater streams because it exhibits the advantages of fast reaction rates, mild operating conditions, and simplicity to control ( Bello et al., 2019). OH, E 0 = 2.80 V/SHE) was generated in situ and found to be capable of degrading any refractory organic molecules present in the aqueous solution until total mineralization at the kinetic constant values as high as 10 8∼10 10 M −1s −1 ( Andreozzi et al., 1999 Oturan and Aaron, 2014 Gao et al., 2018).Over the past few decades, advanced oxidation processes (AOPs) have attracted increasing interests for wastewater treatment since the highly oxidative hydroxyl radical ( ![]() Generally, this combined system was eco-friendly, energy-efficient, and has the potential of being a promising technology for the removal of bio-refractory organic pollutants from wastewaters. In this case, the conductivity just slightly increased from 4.35 to 4.37 mS/cm, minimizing the increase of water salinity, as compared with the conventional Fenton process. Meanwhile, a COD and TOC removal efficiency of 79 and 60% was obtained, respectively. It was found that when a potential of 1.2 V/SCE was applied on the iron cathode, 98% of p-nitrophenol was removed in the combined system after 30 min with continuously adding 200 mg/L of H 2O 2. In an ICEF system, an iron plate was used as the cathode to inhibit the release of iron ions and promote the reduction of Fe 3+ to Fe 2+. In a pH-regulation divided electrolysis system, the desired pH for an effective Fenton reaction and for a neutral treated media could be obtained by H 2O splitting into H + and OH − at the anode and cathode, respectively. In this work, a novel eco-friendly iron cathode electrochemical Fenton (ICEF) system coupled with a pH-regulation divided electrolysis cell was developed. The high consumption of salt reagents and strict pH control are still bottlenecks for the full-scale application of the Fenton reaction. 2Shengli Oilfield Testing and Evaluation Research Co., Ltd., SINOPEC, Dongying, China.1Technical Test Center of Sinopec Shengli OilField, Dongying, China.Xiaohui Wang 1,2* Jingang Zhao 1,2 Chunyan Song 1,2 Xian Shi 1,2 Haipeng Du 1,2
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![]() Video games are the ultimate form of escapism-they can absorb you into their world better than any other form of media. This Roblox Game is Super SadIf you or a friend need help with your mental health, check out the resources here - ️ SUBSCRI.While video game soundtracks are not as artistically acknowledged as other forms of music, sometimes games can have. From visual novels like Phoenix Wright: Ace Attorney to JRPGs like Final Fantasy IX, somber game music always manages to affect player's hearts. 10 Saddest Video Game Songs We Still Love.If you’re the kind of person who gets way too attached to nonhuman characters, particularly animals, way too quickly, brace yourself. This game holds the world record in terms of how quickly it made me cry-within the first five minutes this little heartbreaker had me bawling. ‘Ori and the Blind Forest’ by Moon Studios. Still considered one of the best games ever made, Metal Gear Solid 3 is set in 1964, 31 years prior to the events of the original. It has that classical sad/calm music at a lot of parts in the game.Yes, commit–this doesn’t just involve watching a sad cutscene. Most fans really enjoy the music and the story and regard this as one of the best FF games because of the story and music. It’s an older game, originally released on ps2 but it’s remastered and on modern consoles. Play fullscreen Video Add to My games ️ Save to desktop □.Final fantasy x. Canonical is a short adventure game that follows the sad story of a lonely girl living her miserable life with no light at the end of the tunnel. ![]() It has that classical sad/calm music at a lot of parts in the game.Canonical As the game progresses with each task, the participant reaches the final. A game spread over 50 days, the Blue Whale challenge instructs the participant to complete 50 tasks that include self-harm, watching scary videos, waking at odds hours, etc. A simple trigger can prove disastrous, and even fatal. In this game, you play the role of an observer who captures and spreads images of people's behavior through a camera lens. "We Become What We Behold" is an intriguing and thought-provoking online game that explores the power of media and the impact it has on society. Developer: Team Ico, Sony Interactive Entertainment, SIE Japan Studio. With that being said, let’s kick off this emotional roller-coaster of an article and talk about the saddest video games that will bring forth the onion-cutting ninjas.0:00 Half-Life 2: Episode 20:53 Mafia: Definitive Edition 1:46 Ori and the Blind Forest 2:58 The Walking Dea. 20 of the saddest moments in video game history. Unique to the other games in this list, original voicemails and voice recordings of the parents and other family members. ![]() ![]() In the game, you take the role of the parent with a child diagnosed with cancer. This is an autobiography of two parents who raised their child, Joel, who was diagnosed with cancer at 12 months old. Ghost Trick Phantom Detective took me on an emotional ride, some really sad moments, but the writing can also very cheerful and charming. If you want to be sad, definitely try those. Same as Minecraft Story Mode, there are parts that are sad and depressing.Life is Strange (specifically Episode 4), Undertale, and Sexy Brutale are the only 3 games that made me teared up. What in the hell is supposed to be depressing about it? Maybe that it ends but thats about it. The whole game leaves you with a giant smile on your face. "Tales from the Borderlands" is one of the most upbeat and fun adventure games i ever played. The available characters are Cooper (a gunslinger who can fire two weapons at the same time), McCoy (he acts as a doctor and sniper on the team), Hector (he is a hunter with great strength and can trap enemies), Kate (he can put on disguises and distract opponents) and Isabelle (she is a voodoo priestess and one of her powers is mind control). Desperados III is a story-driven, hardcore tactical stealth game, set in a ruthless Wild West scenario. Each member of the group has unique abilities that will open if you download. Having put together a gang of real thugs, Cooper will visit small towns, swamps and rivers to reach the final goal and take part in a battle worthy of becoming a legend of the Wild West. When left undetected, opponents patrol the maps, and avoiding detection is facilitated by an interface that shows the guards ‘ sight range.Įach squad member has a different specialization and unique equipment and skills. The top 3 reasons to play Desperados III PC. Download Desperados 3 - take part in a legendary battle in the Wild West. Enemies are almost always heavily outnumbered, so success requires a stealth approach and a considerable amount of cunning. On this page you can download save-file for popular Strategy Game - 'Desperados 3'. Desperados, ASCAP/N2D, ASCAP/Pure Blue, BMI) CS 12 H100 71 AMAZING (Please. So we get a real-time tactical strategy in which we command a five-man squad of specialists performing tasks on relatively small maps. 3, 4 (WB Music Corp., ASCAP/So Happy Publishing. ![]() ![]() It involves the command of a band of outlawed specialists with whom he undertakes the most dangerous missions ordered in the Wild West.ĭesperados III remains true to the basic principles governing previous installments, especially part one. Desperados 3 free Download PC About The Game The Gameplay Of The Desperados III Desperados III Download Full Version Similar games: Leave a Reply Cancel. The main character of Desperados III is John Cooper, a gunfighter known from previous episodes of the series. The game is a prequel to the series, although the authors themselves do not shy away from the word reboot either. Find many great new & used options and get the best deals for Desperados 3 PC Steam Key Video Game Instant Download Fast Delivery New at the best online. ![]() It's the Curse of the Bambino, when loyal Red Sox fans live their entire lives without witnessing a championship and when Yankees fans witness four in five years.Īlthough the World Series as we know it didn't begin until 1905, Major League Baseball had several versions of a post-season championship series before that. The World Series is the crushing blow of Fred Snodgrass dropping a routine fly ball and Willie McCovey hitting the final out straight to Bobby Richardson. It's Babe Ruth telling the fans and media where he is going to deposit the next pitch and a heavily outscored team of Pirates beating the unbeatable Yankees off a ninth inning Bill Mazeroski blast. How would one define the World Series? It's Willie Mays catching what can't be caught and Don Larsen being perfect where perfection is simply not possible. It has become the game of all games and has continued to provide us with an endless highlight reel of magical moments evoking childhood memories of agony and ecstasy. Over the last century, the World Series has been woven into the fabric of America's culture evolving far beyond a mere baseball tournament. ![]() An event as important as any holiday on the calendar, it is as traditional as Thanksgiving, as patriotic as the Fourth of July and as anticipated as Christmas morning. Every sport has their pinnacle trophy, but none is as coveted as baseball's World Series a best of seven contest that celebrates our national pastime. WORLD SERIES HISTORY Every World Series in Major League Baseball History | Baseball AlmanacĮach year, the primary focus in any professional sport is the race for a championship. Need help with this service? Contact us for assistance. Embed a spreadsheet - or individual sheets of your spreadsheet - on your blog or website.Chat in real time with others who are editing your spreadsheet while using the online version.Plus, access free Word templates, formatting tools for APA, MLA, and Chicago style, and add functionality with free add-ins. Craft great-looking resumes, newsletters, and documents while inviting others to review and coauthor in real time. Microsoft Excel es el programa de software de hojas de cálculo líder en el sector y una herramienta avanzada de análisis y visualización de datos. Use editing formula to perform calculations on your data, and use formatting to create your own style. Enter your email address and we’ll send a download link.Es un software de hoja de cálculo que permite a los usuarios realizar cálculos, analizar datos y crear gráficos y tablas para presentar información de manera clara y concisa. Select the range of cells, and then type a closing parenthesis). For example, SUM for getting the total sales. Type an equal sign and then type a function. You can use Excel to enter all sorts of data and perform financial, mathematical or. Enter a formula that contains a built-in function. Since Excel 2016, this version has upgraded its. The client communication program is a powerful and helpful tool you can use for data analysis and documentation. ![]() Excel for Windows is part of the Microsoft 365 suite (formerly known as Office 365) but it can be downloaded independently. The program can work on multiple platforms, like Windows, macOS, smartphones, and tablets. Microsoft Excel es una de las herramientas más populares y útiles en el mundo de los negocios, la educación y la investigación. Hundreds of millions of people around the world use Microsoft Excel. Excel 2019 is a spreadsheet program developed by Microsoft. ![]() Spreadsheets present tables of values arranged in rows and columns that can be manipulated mathematically using both basic and complex arithmetic operations and functions. The online version gives you the capability to share and collaborate with others on your files in real-time. Save documents, spreadsheets, and presentations online, in OneDrive. With Office 365, you are able to download the application to your hard drive and will also have access to the online version. Collaborate for free with online versions of Microsoft Word, PowerPoint, Excel, and OneNote. Microsoft Excel is a spreadsheet program included in the Microsoft Office suite of applications. ![]() You absolutely could have a far more evil main character than the game permits, though. I'd also consider the Abyss in its totality a counterargument not just to the idea that it's any kind of analogue to an afterlife (although again it appears that way at first) but to the idea that you've been being given a choice between short and long term gains throughout. There is deliberate narrative and presentational bias here. This seems an unimportant distinction given that the PC is initially presented as a faceless and nameless figure who clearly only exists to provide the player an avatar given the context that the storyline ends up providing, I disagree with that. That said, it's worth noting that the choices and consequences aren't being just presented to the player, but to the player character. Also, I think we disagree at a deep enough level that it's not worth too much effort figuring out exactly where. And I deleted my first two attempts to reply due to either spoilers (since it isn't clear whether you've played through either the main or Abyss storylines) or too much dancing around spoilers. Most of the reasons I'm personally more attracted to this storyline than most of the villain protagonist stuff I've played or read probably wouldn't matter to you, so I'll try to skip over that. ![]() This is as far as my current playthrough has taken me so I will end the whining here, just suffice to say I think this could have been a lot more evil than it actually ended up being. This doesn't send a great message, and I'd even be more ok with leaving it in if there was an option of asking them nicely to leave so we could all end it our own way. ![]() My follow up issues is that I'd love the option of leaving those men to their fate, it's an eternity of suffering for them, seems legit evil to me, at least, I get a kick out of the idea.Īnd then there's that pesky feminism issue that thirteen year old boys will hate me for bringing up. The first is that damn lawn mowing is the most evil thing in this particular abyss and it was inflicted on everyone trying to get passed it. If you got past that lawn, what comes next is "subduing the women" and taking them back to Heaven's Peak. In some cases it's not even evil, and I'm going to use Heaven's Peak Abyss as Exhibit A, I am sure we are all familiar with having to google how to mow that respawning lawn so the abyss in question should come to mind very soon, in case you were scratching your head as to which one it was. Killing someone is arguably a mercy when what is in store is slave labour, I think the Evil Vs More Evil choices are the wrong way around here. Albeit this one is targeted at a much younger audience. ![]() It's a fun old game and it still holds up today and I (admittedly) do have fond memories of hours spent playing it on consoles.Įvil vs More Evil is really just a choice here about long term gains over short term gains, in that order.Ī way of saying "yes, you can be edgy and cool and kill everyone, but there's less reward for it in the end", and I'm sure I'm not the only one who has seen the outrage over Mass Effect's same simplistic game design. This game and its idea of evil truly dissapoints me. Let's find out just how dead and dusty these forums are!īefore I go ahead and spend an hour crafting the perfect post so anyone who does come along doesn't bother to read it and simply comments "no", I'm diving right in. Google said they are aware of the problem and working on a fix for the same. The ability to create a “Home Entry Only” member is missing on the web app, so make sure you do so before using the Nest web app to “Edit the schedule.” SourceĪpart from letting users create passcodes for guests, another bug haunting Nest X Yale users is the ability to control the Yale lock using the Nest app. However, you will need to create the Guest Passcode using the app. If you want to set the start and end times for your guest passcodes, you can use the Nest web app () to set the guest passcodes. Please I need help asap.įortunately, the company has provided a workaround that might come in handy for some. Can not choose date and time for further activations to come anymore. I use the Yale door lock since more than 2 years now and I’m having trouble to set it up for visitors. I’ve tried closing out of the app and looking for app updates, but it says everything is up to date. I have to leave their passcode active until I manually go back in and delete it. Previously I would click “start” and a rolling wheel of hours/AM PM would drop down. I’m an Airbnb host, so this was a great feature. The Nest app for the Yale logo used to let me set a start/stop time for guest passcodes. However, the company has not provided any ETA on when the issue will be fixed. Google said that they are already aware of the issue and working on a fix. However, the Nest app on iOS devices has achieved this astonishing feat.Īccording to several user reports, the Nest app for Yale locks no longer allows users to set a start or stop time for guest users. Having said that, it is rare for such a critical app to mess things up. It allows you to lock your door keyless, set timers for guests, create a new entry for anyone entering your property, set passcodes, and even comes with an activity log. The Nest x Yale is one of the most popular key-less smart-lock solutions on the internet.Īll you need is the Nest x Yale lock and a screwdriver, and you are good to go. One of the most hassle-free ways to do so is by installing a smart lock. ![]() If you happen to own a building or an Airbnb place, you must have thought of improving the security while allowing access to the people who are staying there. Bake for 15-18 minutes or until golden brown on top.Copycat Jiffy Corn Muffin Mix is super easy to make right in your own kitchen!.BEING EXTREMELY CAREFUL SO AS NOT TO GET BURNED, remove hot skillet from oven and pour in batter.Very gently fold in drained blueberries, trying not to break the berries as they’ll stain the batter purple.Add buttermilk mixture to Jiffy Corn Muffin mixture and stir until there are no dry spots but try not to stir too much.I use a small whisk to break up the yoghurt. In a small bowl mix buttermilk, yoghurt, honey or molasses and egg.In a large bowl mix all the dry ingredients breaking up any large lumps and set aside.Drain blueberries in a colander and lightly rinse to get off any excess purple syrup.Pour oil into pan and swirl it around making sure to cover all the bottom and up the sides.a scant 1/4 cup of canola oil for the pan.1 15 ounce can blueberries in LIGHT syrup, I use Oregon brand.1/4 cup plain Greek yoghurt, I use Fage non-fat.Just add 12-15 minutes to your baking time. It’s really good the next day, too, cold. And your family can snack on it through the day until dinner is served. You could easily serve this Thanksgiving morning with bacon for breakfast. It will give you a crispy, salty crust that will make your head spin. You’ll love it! And use your cast iron pan. ![]() But you could use peaches, canned, fresh or frozen. And it’s so good-looking! Deep purple against that soft yellow is just lovely. Other than those pointers it’s pretty simple. If you’re wondering why I didn’t use frozen it’s because I think they would start defrosting while folding them into the mix and their juices would turn the batter purple. And, of course, be very gentle when stirring them in and keep the mixing down to a bare minimum. Just make sure the berries are well-drained after softly rinsing them well in a colander. ![]() Since I won’t pay $6.00 for that little, crappy container of fresh blueberries at the grocery store I opted for canned blueberries in a light syrup. ![]() I thought, “I can do this and do it my way.” So I did. A firm embracer of “waste not, want not”, I tasted it. I wasn’t going to even try the cornbread because of the blueberries but she had purchased these things at Whole Foods and probably paid $9.00 for that little chunk of bread. I had been feeling puny so the soup really hit the spot. I’m not one to put any kind of fruit in cornbread…I had always thought that just ruined it until this week when my friend Janey brought over some soup, blueberry cornbread and a HUGE dark chocolate candy bar studded with almonds. To cut some of that heat I wanted a rich, sweet cornbread. Since this pot was only for Jimmy and me I made it much spicier than usual adding more vinegar and quite a bit more red pepper flakes. And resting on top of my greens I wanted a thick chunk of cornbread. I wanted collards for dinner, masses of thin, green ribbons slow simmered in a gorgeous pot likker seasoned with bits of smoked ham, chopped onion, vinegar and red pepper flakes. Ever had cornbread that’s so darned rich it’s really corn CAKE? Well, that’s what I made the other night. And, since the occasion itself won’t be understandable to the infant, cuddly stuffed animals always make great personalized baptism gifts. Celebrate baby girls Baptism with classic Precious Moments artwork by artist and founder Samuel J. Choose from keepsake boxes, godchild frames and plenty more to find the perfect personalized gift for the people who have such an important role in your child’s spiritual life.īaptism gifts for boys and girls are literally at your fingertips! Many are available in pink or blue - or perhaps you go neutral with a soft white blanket. Gifts for godparents may also be on your shopping list, and Personal Creations is your source for those, too. ![]() We know you’ll find what you’re looking for when you browse our vast selection of baptism gifts - one of them is bound to hit the mark!Religious gifts also make unique first birthday gift ideas as well! Whether you’re looking for inspiration for new party activities or you’re shopping for party supplies near you, we’ve got what you need, and you can shop online or in-store. Plenty of religious gifts are suitable to celebrate a baptism, including personalized Bibles and rosary gifts. Hallmark is here for you, with tons of party-planning ideas and themes, as well as a fresh new collection of party supplies. From commemorative wall art and blessing blankets to frames and christening bibs, our baby baptism gifts are solemn yet cheerful reflections of the big event. You’ll find a wide range of baptism gifts featuring the most traditional symbol of the faith: the cross. Precious Moments Girl - Baptism Napkin classicpreciousmoments cute adorable baptism classicretro napkins wedding anniversary birthday reception. ![]() At Personal Creations, we put the joy in this joyous occasion with thoughtful personalized baptism gifts that will serve as lifelong reminders of such a special day. ![]() Looking for appropriate baptism gifts for boys and girls? You’ve come to the right place. Personalized Baptism Gifts - Keepsakes to Cherish Forever ![]() I tried transferring a ~950MB video file to my iPhone, and it took a little over 5 minutes to complete, which means that data transfer was ~3MBps (yes, Megabytes). The speed that Send Anywhere got was good, especially considering the fact that it was a wireless transfer, over a network that doesn’t really run that fast. While the app does show the time remaining, it doesn’t show the speed of transfer, which is why I had to use a crude stopwatch method to check that. Fortunately, the app displays the progress in percentage, and in the amount of data transferred. Recognition is nice and fast, and the files begin transferring quickly.Here, you can either enter the 6-digit key, or tap on the QR code icon on the top right, and scan the QR code being displayed on the desktop app. On the iOS app, you can simply head over to the “Receive” tab.With the web widget you can effortlessly transfer files up to 2GB in size! This will generate a 6-digit key, as well as a QR code, which you can then use to transfer the files directly from the browser. However, the best part is the web widget. You can just go to the Send-Anywhere website, and add the files you want to send. It’s really great, and very intuitive, and you’ll never really need to use the Videos app to play your videos again.ħ. The Send Anywhere video player offers features like swiping to seek the video, swiping up/down on the left side to adjust brightness, and on the right side to adjust volume. The video player in the iOS app is where things really get awesome. The music app offers functionality like sharing the song, using AirPlay to stream it to an Apple TV and more.Ħ. ![]() So, you can just send yourself a music file, and directly play it in Send Anywhere. Another cool thing in Send Anywhere are the music and video players that are built right into the iOS app. This is known as “ Quick Link Share“, and it’s awesome!ĥ. What’s more, if you’re using Send Anywhere on your Android device, you can generate the link directly from your favourite messenger. This is a useful feature for sending files to people who may not have Send Anywhere installed. In the “Share Link” method, you get a link which you can share with the receiver, and they can simply go there and download the files within 48 hours. This method is awesome because the receiver doesn’t need to have Send Anywhere installed. Another really cool way of sharing files with Send Anywhere is “Share Link”. Send-Anywhere can easily remove the 20MB attachment limit, and increase it to 10GB.Ĥ. There’s also an Outlook Mail Add-in, if that’s your preferred email client. With the Chrome Extension, you won’t need to adhere to the 25 MB attachment limit that Gmail sets in email attachments Send Anywhere can directly send files up to 10 GB in size to the recipient.ģ. Send Anywhere has apps for almost every platform out there… heck, it’s also available for Windows Mobile!Ģ. First, the app can be used to transfer files between devices running on different platforms, without the usual restriction of email attachment sizes, or the poor speed of WiFi. Since the app supports so many platforms, it is already in a good place as far as my opinion goes, and an app like this obviously has a lot of use cases, and a lot of ways in which it can be used.ġ. Send Anywhere supports “WiFi Direct” on Android, which basically allows you to leverage the full speed of WiFi networks, without using a single byte of your data, it’s awesome, and can really come in handy for large file transfers. The Android app is a lot similar in design, and chooses to separate different file types in separate tabs, while keeping the “Send”, “Receive”, and “Activity” functions in a bottom navigation menu. On the iOS app, Send Anywhere chooses to separate file types into separate tabs, with the functions for sending/receiving files, viewing the activity, and “more” options in their own tabs. The desktop app comes with a clean interface with well arranged regions for sending/receiving buttons, nearby devices, and the transferred files, if any. Launching the app for the first time, I was pretty happy to see the well-designed, minimal interface, along with a naming scheme that makes the functions of every option very clear. ![]() Since the app supports macOS, and iOS, I decided to try it out on my MacBook Air, running macOS Sierra 10.2.3, and my iPhone running iOS 10.3.2 Public Beta. The application solves this by supporting a large number of platforms, and extending file size limits to an extent where it becomes basically unlimited for most use-cases you may encounter. ![]() Send Anywhere is an application born out of the need to solve the very common problem of transferring large files between devices. |
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